ACEDIN FORM 171 Safety Data Sheet

	According to 2001/58/EC
	MATERIAL SAFETY DATA SHEET
	Catalogue N° : 01826D07 Printing date : 20/05/2007

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1. Identification of the substance or preparation
ACEDIN FORM 171

1.2. Use of the substance/preparation Fountain additive for offset printing. 1.3. Company/undertaking identification FUJIFILM Europe NV EUROPARK-NOORD 21-22 B-9100 SINT NIKLAAS TEL : +32 (3)760 02 00 FAX : +32 (3)776 91 22 1.4. Emergency telephone +32 (0)3 760 02 00
2. COMPOSITION / INFORMATION ON INGREDIENTS
Aqueous solution. Components contributing to hazard:

w/w%	CAS N°	EINECS N°	`Chemical Name Symb.R-phrases`
3-7 . 1-5 . 1-5 . <0,1 . <0,1 . 0,1-1 .	112-34-5 . 97-64-3 . 111-76-2 . 26172-55-4 . 2682-20-4 . 52-51-7 .	203-961-6 . 202-598-0 . 203-905-0 . 247-500-7 . 220-239-6 . 200-143-0 .	2-(2-BUTOXYETHOXY)ETHANOL Xi R:36 ETHYL-L-LACTATE Xi R:10-37-41 2-BUTOXYETHANOL Xn R:20/21/22-36/38 5-CHLORO-2-METHYL-2H-ISOTHIAZOLIN-3-ONE T N R:23/24/25-34-43-50/53 2-METHYL-2H-ISOTHIAZOLIN-3-ONE T N R:23/25-34-43-50 BRONOPOL XnN R:21/22-37/38-41-50

3. HAZARDS IDENTIFICATION
Most important hazards : Irritating to eyes. May cause sensitization by skin contact.
4. FIRST AID MEASURES
Eye contact Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel. Skin contact Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing Ingestion Consult a physician or transport to emergency facility immediately Inhalation Remove to fresh air. Consult a physician. Further information Overexposure may lead to allergic skin reactions with sensitized people. In this case, seek medical advice.
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media: Water. Water fog, carbon dioxide, foam, dry chemicals. 5.2. Extinguishing media to avoid: None under normal conditions. 5.3. Further information: Keep containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure control / personal protection ). - Spills should be contained by and carried with suitable absorbent material and removed from disposal. - Dispose of according to local and national regulations. - Prevent from entering into soil, waterways and groundwater.
7. HANDLING AND STORAGE
7.1. Handling Avoid eye and skin contact. Wash hands and exposed skin before eating, drinking or smoking and after work. Use only in a well ventilated area. Ingestion, exposure to skin and eyes and inhalation of any generated vapours should be avoided. Wear suitable protective clothing, gloves and eye/face protection. Do not consume or store food in the working area. 7.2. Storage Keep containers tightly closed. Store in a well ventilated, cool, dry area. Storage class : 12 (VCI storage system).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION) 2-(2-BUTOXYETHOXY)ETHANOL MAK ( Deutschland, TRGS 900 ) = 100 mg/mł TLV-TWA = NAv ETHYL-L-LACTATE MAK ( Deutschland, TRGS 900 ) = NAv 2-BUTOXYETHANOL MAK ( Deutschland, TRGS 900 ) = 20 ppm - 98 mg/mł TLV-TWA = 25 ppm - 123 mg/mł 5-CHLORO-2-METHYL-2H-ISOTHIAZOLIN-3-ONE MAK ( Deutschland, TRGS 900 ) = 0,2 mg/mł(mixture CIT/MIT 3:1) 2-METHYL-2H-ISOTHIAZOLIN-3-ONE MAK ( Deutschland, TRGS 900 ) = 0,2 mg/mł(mixture CIT/MIT 3:1) BRONOPOL MAK ( Deutschland, TRGS 900 ) = NA 8.2. Exposure controls Respiratory protection: no respiratory protection needed under normal conditions. Good ventilation should be sufficient. Hand protection: use chemical resistant gloves. In case of prolonged immersion or frequently repeated contact use gloves made of the materials: nitrile rubber (thickness >= 0,38 mm, breakthrough time > 480 min) neoprene (thickness >= 0,65 mm, breakthrough time > 240 min). butyl rubber (thickness >= 0,36 mm, breakthrough time > 480 min) For intermittent splash protection corresponding gloves with breakthrough time > 60 min can be used. Avoid gloves made of : natural rubber. Eye protection: use chemical safety goggles. Eye wash fountain should be located in immediate work area. Other: appropriate protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid Colour : Yellow Odour : Mild Boiling point/range : ~ 100°C Density (20°C) Kg/L : 1,09 pH value (25°C) : 4,70 Vapour pressure (20°C) : ~ 23 mbar Solubility in water (25°C) : Completely Soluble

10. STABILITY AND REACTIVITY
10.1. Conditions to avoid The product is stable under normal storage conditions. 10.2. Materials to avoid None. 10.3. Hazardous decomposition products Formation of CO2 and CO fumes is possible.
11. TOXICOLOGICAL INFORMATION
Acute toxicity (INGREDIENTS INFORMATION) 2-(2-BUTOXYETHOXY)ETHANOL LD50 (Oral Rat) = 5660 mg/kg ETHYL-L-LACTATE LD50 (Oral Rat) = > 2500 mg/kg LC50 (Inhalation rat) = > 5400 mg/m3/8h 2-BUTOXYETHANOL LD50 (Oral Rat) = 470 mg/kg LD50 (Dermal rabbit) = 220 mg/kg LC50 (Inhalation rat) = 2900 mg/L/4h 5-CHLORO-2-METHYL-2H-ISOTHIAZOLIN-3-ONE LD50 (Oral Rat) = NAv 2-METHYL-2H-ISOTHIAZOLIN-3-ONE LD50 (Oral Rat) = 285 mg/kg LD50 (Dermal rabbit) = > 2000 mg/kg BRONOPOL LD50 (Oral Rat) = 254 mg/kg LD50 (Dermal rabbit) = 1600 mg/kg Eye contact Irritating to eyes. Skin contact May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity 2-(2-BUTOXYETHOXY)ETHANOL LC50 (Fish, 96 hours) = NAv ETHYL-L-LACTATE LC50 (Fish) = 320 mg/l/48h EC50 ( 96hrs, Algae ) = 2200 mg/l 2-BUTOXYETHANOL LC50 (Goldfish, 24h) = 1650 - 1700 mg/L LC50 (Bluegill, 96h) = 1490 mg/L LC50 (Daphnia magna straus, 24h) = 1720 mg/L 5-CHLORO-2-METHYL-2H-ISOTHIAZOLIN-3-ONE LC50 (Fish, 96 hours) = NAv 2-METHYL-2H-ISOTHIAZOLIN-3-ONE LC50 (Fish, 96 hours) = NAv LC50 (Daphnia, 48h) = 1,6 mg/l BRONOPOL LC50 (Rainbow trout, 96h) = 41,2 mg/L LC50 (Daphnia, 48h) = 1,4 mg/L EC50 ( 96hrs, Algae ) = 0,4-2,8 mg/L 12.2. Mobility not known 12.3. Persistence and Degradability
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be disposed of in accordance with local regulations. EWC: 07 07 99 Wastes not otherwise specified
14. TRANSPORT INFORMATION
ADR/RID Class:NA labels :- Pack. Group:- Code :NA TREMcard :NA Spec. Prov.:- Pack. Inst.:- Lim. Quant.:- IMDG Class:NA Subs. Risk :NA Pack. Group:NA EmS fire:NA EmS Storage:NA IBC. Inst. :- Pack. Inst.:- Lim. Quant.:- Mar.Poll:N ICAO/IATA Class:NA Subs. Risk :NA Pack. Group:NA Passenger and Cargo Aircraft. Pkg Inst:NA Max Net Qty/Pkg:NA Cargo Aircraft Only . Pkg Inst:NA Max Net Qty/Pkg:NA Ltd Qty . Pkg Inst:- Max Net Qty/Pkg:-
15. REGULATORY INFORMATION
EU Classification and User Label Information: Contains : 5-CHLORO-2-METHYL-2H-ISOTHIAZOLIN-3-ONE 2-METHYL-2H-ISOTHIAZOLIN-3-ONE Symbol(s) : Xi R(isk) phrase(s) : R36 : Irritating to eyes. R43 : May cause sensitization by skin contact. S(afety) phrase(s) : S24 : Avoid contact with skin. S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 : Wear suitable gloves. Other information : WGK: 1 BAG T n° (CH): 681 084 Toxicity class (CH): 4

16. OTHER INFORMATION
The use of the preparation is restricted to professional users| The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications have not the meaning of guarantees on properties. --------------------------------------------------------------------------- Date of issue: 01.04.2004 Supersedes edition of - --------------------------------------------------------------------------- NAv : Not available NA : Not applicable RISK PHRASES MENTIONED IN PARAGRAPH 2: R10 : Flammable. R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R21/22 : Harmful in contact with skin and if swallowed. R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R23/25 : Toxic by inhalation and if swallowed. R34 : Causes burns. R36 : Irritating to eyes. R36/38 : Irritating to eyes and skin. R37 : Irritating to respiratory system. R37/38 : Irritating to respiratory system and skin. R41 : Risk of serious damage to eyes. R43 : May cause sensitization by skin contact. R50 : Very toxic to aquatic organisms. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.